Wednesday, 18 May 2016

2.38 describe tests for the anions...

Halide ions
To test for halide ions, add dilute nitric acid (HNO3) followed by silver nitrate solution (AgNO3). A precipitate will be produces, the colour of this precipitate will determine what ions are present.
Cl -  > white precipitate
Br- > cream precipitate
I-   > yellow precipitate

NOTE: The silver nitrate solution determines which halide ions are present. The dilute nitric acid is added to 'get rid' of an carbonate or sulphite ions (as these would react with the silver nitrate).


Sulphate ions
To test for sulphate ions (SO42- ), add dilute HCl and then barium chloride solution (BaCl2). If sulphate ions are present, a note precipitate would form (this precipitate is barium sulphate)

NOTE: The HCl is used to 'get rid' of any carbonate ions, and these may impede results if present as they would also produce a precipitate).


Carbonate ions
To test for carbonate ions (CO32- ), add dilute HCl to the sample you are testing. If a gas is produced, collect it and bubble it through limewater. If carbonate ions are present, the limewater will go cloudy as carbon dioxide will be released.

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